Quick A: If there is an initializer list contructor, it will choose it.
Recently on SO:
When an argument is an initializer list ([dcl.init.list]), it is not an expression and special rules apply for converting it to a parameter type.
If the parameter type is std::initializer_list or “array of X” and all the elements of the initializer list can be implicitly converted to X, the implicit conversion sequence is the worst conversion necessary to convert an element of the list to X. This conversion can be a user-defined conversion even in the context of a call to an initializer-list constructor.
Otherwise, if the parameter is a non-aggregate class X and overload resolution per [over.match.list] chooses a single best constructor of X to perform the initialization of an object of type X from the argument initializer list, the implicit conversion sequence is a user-defined conversion sequence. If multiple constructors are viable but none is better than the others, the implicit conversion sequence is the ambiguous conversion sequence. User-defined conversions are allowed for conversion of the initializer list elements to the constructor parameter types except as noted in [over.best.ics].